OBSERVATION OF CLO3 RADICAL IN AQUEOUS CHLORATE SOLUTION BY PULSE-RADIOLYSIS

被引：18

作者：

DOMAE, M ^{[1
]}

KATSUMARA, Y ^{[1
]}

JIANG, PY ^{[1
]}

NAGAISHI, R ^{[1
]}

HASEGAWA, C ^{[1
]}

ISHIGURE, K ^{[1
]}

YOSHIDA, Y ^{[1
]}

机构：

[1] UNIV TOKYO,FAC ENGN,NUCL ENGN RES LAB,IBAKAKI 31911,JAPAN

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1994年 / 98卷 / 01期

关键词：

D O I：

10.1021/j100052a031

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A pulse radiolysis study on concentrated aqueous chlorate solution was carried out. In the radiolysis of the chlorate system, ClO2 and ClO3 radicals are produced as a result of direct action of radiation on chlorate ion with G values of 1.0 and 1.5, respectively, whereas the slow formation process of ClO3 radicals is not observed. The absorption peak Of ClO3 radicals is around 330 +/- 10 nm and the absorption coefficient is evaluated as 4700 M-1 cm-1. The rate constants of some reactions of ClO3 radical with additives were determined.

引用

页码：190 / 192

页数：3

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