ONE-POT AND SELECTIVE SYNTHESIS OF A SERIES OF [RUCL6-2NLN] (L = BIDENTATE LIGAND, N = 0-3) TYPES OF COMPLEXES WITH POLYPYRIDYL LIGANDS - ANOTHER EXAMPLE OF THE SYNTHETIC UTILITY OF RUTHENIUM-BLUE SOLUTION

被引：66

作者：

TOGANO, T

NAGAO, N

TSUCHIDA, M

KUMAKURA, H

HISAMATSU, K

HOWELL, FS

MUKAIDA, M

机构：

[1] SOPHIA UNIV,FAC SCI & TECHNOL,DEPT CHEM,KIOI CHO 7-1,CHIYODA KU,TOKYO 102,JAPAN

[2] TOHOH GIRLS HIGH SCH,CHOFU,TOKYO 182,JAPAN

来源：

INORGANICA CHIMICA ACTA | 1992年 / 195卷 / 02期

关键词：

D O I：

10.1016/S0020-1693(00)85316-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Convenient (one-pot) and selective syntheses of a series of ruthenium complexes with polypyridyl ligands, [RuL3]2+, cis-[RuCl2L2]+ and [RuCl4L]- (L=bpy, phen or Hdpa (di-2,2-dipyridylamine)), including [RuCl6]3-, have been reported as further examples of the synthetic utility of 'ruthenium-blue' solution. The methods developed here are also useful for synthesizing selectively such pair complexes as [Ru(III)Cl3(terpy)]-[Ru(II)(terpy)2]2+ and [Ru-(III)Cl4py2]--[Ru(II)Cl2py4].

引用

页码：221 / 225

页数：5

共 38 条

[1]

ANDERSON S, 1979, J CHEM RES S, P74

[2] SYNTHESIS AND PROPERTIES OF OXO COMPLEX OF RUTHENIUM(IV), TRANS-[RUCL(O)(PY)4]+, WHICH IS FORMED BY THE OXIDATION OF NITROSYL COMPLEX OF RUTHENIUM(II), TRANS-[RUCL(NO)(PY)4]2+ [J].