A VERSATILE OXIDIZING-AGENT - TETRAKIS-PYRIDINO-COBALT(II) DICHROMATE PY4CO(HCRO4)2 (TPCD) - OXIDATIONS OF ALCOHOLS, HALIDES AND AMINES TO THEIR CORRESPONDING CARBONYL-COMPOUNDS

被引：27

作者：

HU, YF

HU, HW

机构：

[1] Department of Chemistry, Nanjing University

来源：

SYNTHETIC COMMUNICATIONS | 1992年 / 22卷 / 10期

关键词：

D O I：

10.1080/00397919208021618

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The preparation of a versatile oxidizing agent tetrakis-pyridino-cobalt (II) dichromate Py4Co(HCrO4)2 (TPCD) is presented and its structure is confirmed by x-ray crystal data. Alcohols, halides and amines are oxidized smoothly to their corresponding carbonyl compounds in good yields with TPCD.

引用

收藏

页码：1491 / 1496

页数：6

相关论文

共 13 条

[1] PYRIDINIUM FLUOROCHROMATE - A NEW AND EFFICIENT OXIDANT FOR ORGANIC SUBSTRATES [J].

BHATTACHARJEE, MN ;

CHAUDHURI, MK ;

DASGUPTA, HS ;

ROY, N ;

KHATHING, DT .

SYNTHESIS-STUTTGART, 1982, (07) :588-590

[2]

CAINELLI G, 1984, CHROMIUM OXIDATIONS, P246

[3]

CARDILLO G, 1976, TETRAHEDRON LETT, P3985

[4] CHROMATE ION AS A SYNTHETICALLY USEFUL NUCLEOPHILE - NOVEL SYNTHESIS OF ALDEHYDES FROM ALKYL-HALIDES [J].

CARDILLO, G ;

ORENA, M ;

SANDRI, S .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1976, (06) :190-190

[5]

COLLINS JC, 1968, TETRAHEDRON LETT, P3363

[6]

COREY EJ, 1975, TETRAHEDRON LETT, P2647

[7]

COREY EJ, 1979, TETRAHEDRON LETT, P399

[8] REAGENTS AND SYNTHETIC METHODS .64. PYRIDINE ASSISTED OXIDATIONS OF ALCOHOLS TO CARBONYL-COMPOUNDS BY MEANS OF 3-CARBOXYPYRIDINIUM DICHROMATE (NDC) REAGENT [J].

COSSIO, FP ;

LOPEZ, MC ;

PALOMO, C .

TETRAHEDRON, 1987, 43 (17) :3963-3974

[9] TETRAKIS(PYRIDINE)SILVER DICHROMATE PY4AG2CR2O7 - A MILD AND EFFICIENT REAGENT FOR THE CONVERSION OF BENZYLIC AND ALLYLIC ALCOHOLS TO THEIR CORRESPONDING CARBONYL-COMPOUNDS [J].

FIROUZABADI, H ;

SARDARIAN, A ;

GHARIBI, H .

SYNTHETIC COMMUNICATIONS, 1984, 14 (01) :89-94

[10]

GUZIEC FS, 1980, SYNTHESIS-STUTTGART, P691