CALCULATIONS OF ELECTRON INELASTIC MEAN FREE PATHS .5. DATA FOR 14 ORGANIC-COMPOUNDS OVER THE 50-2000 EV RANGE

被引:2037
作者
TANUMA, S [1 ]
POWELL, CJ [1 ]
PENN, DR [1 ]
机构
[1] NATL INST STAND & TECHNOL,GAITHERSBURG,MD 20899
关键词
D O I
10.1002/sia.740210302
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We report calculations of electron inelastic mean free paths (IMFPs) of 50-2000 eV electrons for a group of 14 organic compounds: 26-n-paraffin, adenine, beta-carotene, bovine plasma albumin, deoxyribonucleic acid, diphenylhexatriene, guanine, kapton, polyacetylene, poly(butene-1-sulfone), polyethylene, polymethylmethacrylate, polystyrene and poly(2-vinylpyridine). The computed IMFPs for these compounds showed greater similarities in magnitude and in the dependences on electron energy than was found in our previous calculations for groups of elements and inorganic compounds (Papers II and III in this series). Comparison of the IMFPs for the organic compounds with values obtained from our predictive IMFP formula TPP-2 showed systematic differences of approximately 40%. These differences are due to the extrapolation of TPP-2 from the regime of mainly high-density elements (from which it bad been developed and tested) to the low-density materials such as the organic compounds. We analyzed the IMFP data for the groups of elements and organic compounds together and derived a modified empirical expression for one of the parameters in our predictive IMFP equation. The modified equation, denoted TPP-2M, is believed to be satisfactory for estimating IMFPs in elements, inorganic compounds and organic compounds.
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页码:165 / 176
页数:12
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