PREPARATION AND CHARACTERIZATION OF A PALLADIUM-COPPER HETEROMETALLIC COMPLEX AND ITS CATALYTIC ACTIVITY TOWARDS OXIDATION OF ALKENES

被引:16
作者
HOSOKAWA, T [1 ]
TAKANO, M [1 ]
MURAHASHI, S [1 ]
OZAKI, H [1 ]
KITAGAWA, Y [1 ]
SAKAGUCHI, K [1 ]
KATSUBE, Y [1 ]
机构
[1] OSAKA UNIV,INST PROT RES,SUITA,OSAKA 565,JAPAN
关键词
D O I
10.1039/c39940001433
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Treatment of PdCl2(MeCN)(2) and CuCl2 with pyrrolidin-2-one L gives a novel Pd-Cu heterometallic complex having a polymeric structure of [ClCu(L)(4)(mu-Cl)PdCl2.PdCl2](n) which catalyses the oxidation of cyclohexene in ClCH2CH2Cl-MeOH.
引用
收藏
页码:1433 / 1434
页数:2
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