ANIONIC, 4-COORDINATE, 10-ELECTRON BISMUTH COMPLEXES

被引：19

作者：

CLEGG, W

COMPTON, NA

ERRINGTON, RJ

FISHER, GA

HOCKLESS, DCR

NORMAN, NC

ORPEN, AG

机构：

[1] UNIV NEWCASTLE UPON TYNE,DEPT CHEM,NEWCASTLE TYNE NE1 7RU,TYNE & WEAR,ENGLAND

[2] UNIV BRISTOL,DEPT INORGAN CHEM,BRISTOL BS8 1TS,AVON,ENGLAND

来源：

POLYHEDRON | 1991年 / 10卷 / 01期

关键词：

D O I：

10.1016/S0277-5387(00)83559-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and structures of [PPN][BiCl2{Fe(CO)2(eta-C5H5)}2] and [PPN][BiCl2{Mo(CO)3(eta-C5H5)}2] (PPN = Ph3PNPPh3) are described; both bismuth complexes adopt structures intermediate between tetrahedral and equatorially vacant trigonal bipyramidal, possible electronic reasons for which are presented and discussed.

引用

页码：123 / 126

页数：4

共 16 条

[1]

Albright T.A., 1985, ORBITAL INTERACTIONS, P268

[2] SYNTHETIC AND STRUCTURAL STUDIES ON ORGANOMOLYBDENUM AND ORGANOTUNGSTEN COMPLEXES CONTAINING BISMUTH - X-RAY CRYSTAL-STRUCTURES OF [BICL(MO(CO)3(ETA-C5H5))2] AND [BICL(MO(CO)2(CNBUT)(ETA-C5H5))2] [J].