MN-55, C-13 COUPLING-CONSTANTS OF SOME SIGMA-ORGANOMANGANESE AND PI-ORGANOMANGANESE COMPLEXES

被引：11

作者：

TOROCHESHNIKOV, V ^{[1
]}

RENTSCH, D ^{[1
]}

VONPHILIPSBORN, W ^{[1
]}

机构：

[1] UNIV ZURICH,INST ORGAN CHEM,CH-8057 ZURICH,SWITZERLAND

来源：

MAGNETIC RESONANCE IN CHEMISTRY | 1994年 / 32卷 / 06期

关键词：

NMR; (13)CNMR; MN-55; (1)J(MN-55; C-13); ORGANOMANGANESE COMPLEXES; LINESHAPE ANALYSIS;

D O I：

10.1002/mrc.1260320607

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mn-55, C-13 coupling constants of sigma- and pi-organomanganese pentacarbonyl, tetracarbonylphosphine and tricarbonyl complexes were determined by lineshape analysis of the (CO)-C-13 and C-13(R) signals (R = alkyl, acyl or aryl) using the iterative lineshape fitting program QUADR. The (1)J(Mn-55,C-13) data are in the range 29-47 Hz for Mn-CO bonds and 2-28 Hz for Mn-R bonds. The Mn-55 chemical shifts and linewidths are also reported.

引用

页码：348 / 352

页数：5

共 31 条

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