CRYSTAL-STRUCTURE OF [NA.3THF][FE(CO)3(SEPH)3] AND [N(PPH3)2][FE(CO)3(SEPH)3].0.5THF (THF = TETRAHYDROFURAN) - EVIDENCE FOR NA+ ... SEPH AND LONG-RANGE NA+ ... FEII INTERACTIONS

被引：23

作者：

LIAW, WF ^{[1
]}

LAI, CH ^{[1
]}

LEE, CK ^{[1
]}

LEE, GH ^{[1
]}

PENG, SM ^{[1
]}

机构：

[1] NATL TAIWAN UNIV,DEPT CHEM,TAIPEI,TAIWAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1993年 / 15期

关键词：

D O I：

10.1039/dt9930002421

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction between Na[HFe(CO)4] and (PhSe)2 yielded Na[Fe(CO)3(SePh)3] which crystallized as [Na-3thf][Fe(CO)3(SePh)3] in which three tetrahydrofuran (thf) molecules and the [Fe(CO)3(SePh)3]-anion surround the sodium cation; in the corresponding crystal structure of [N(PPh3)2][Fe(CO)3-(SePh)3].0.5thf the cations and anions are discrete entities.

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页码：2421 / 2422

页数：2

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