PREPARATION OF FE3O4 FINE PARTICLES THROUGH A SOLVOTHERMAL PROCESS

被引：30

作者：

DUBOIS, T ^{[1
]}

DEMAZEAU, G ^{[1
]}

机构：

[1] UNIV BORDEAUX 1,ENSCPB,LCS,CNRS,F-33405 TALENCE,FRANCE

来源：

MATERIALS LETTERS | 1994年 / 19卷 / 1-2期

关键词：

Crystal growth - Ferromagnetic materials - Iron oxides - Synthesis (chemical);

D O I：

10.1016/0167-577X(94)90102-3

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A so-called solvothermal process, which differs in several aspects from the hydrothermal synthesis, has been used to prepare Fe3O4 fine particles well defined in size and morphology. The nature of the solvent and its physical properties in the supercritical state, the choice of the precursor, as well as the pressure and temperature domains have led to the control of the nucleation and crystal growth of the microcrystallites with a specific shape. Using iron oxide hydroxide (FeOOH) as the precursor and a mixture of water and ethanol, which has reducing properties as a solvent, fine particles with an octahedral morphology and a size of about 1 mum have been prepared.

引用

页码：38 / 47

页数：10

共 11 条

[1] GOUW TH, 1975, ADV CHROMATOGR, V13, P1
[2] HOY KL, 1970, J PAINT TECHNOL, V42, P76
[3] HUGGET J, 1929, LIEBIGS ANN CHEM, V10, P445
[4] IPATIEW W, 1926, BER DEUT CHEM GESELL, V59, P1421
[5] IRANI CA, 1977, RECENT DEV SEPARATIO, V171
[6] MICHEL A, 1967, NOUVEAU TRAITE CHIMI, V17, P615
[7] INFLUENCE OF POTASSIUM ON THE NUCLEATION AND EARLY GROWTH OF MAGNETITE IN THE REDUCTION OF HEMATITE WITH CARBON-MONOXIDE CARBON-DIOXIDE
ROEDERER, J
DUPRE, B
GLEITZER, C
[J]. REACTIVITY OF SOLIDS, 1987, 3 (1-2): : 45 - 55
[8] THE GROWING OF SINGLE CRYSTALS OF MAGNETITE
SMILTENS, J
[J]. JOURNAL OF CHEMICAL PHYSICS, 1952, 20 (06) : 990 - 994
[9] Smith R.D., 1986, US Patent, Patent No. [4582731, 4,582,731]
[10] SNOEK E, 1947, NEW DEV FERROMAGNETI, V24

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