KINETICS OF DIACETYLENE POLYMERIZATION - AN FT-RAMAN STUDY

被引：26

作者：

KAMATH, M

KIM, WH

LI, L

KUMAR, J

TRIPATHY, S

BABU, KN

TALWAR, SS

机构：

[1] UNIV MASSACHUSETTS,CTR ADV MAT,DEPT CHEM,LOWELL,MA 01854

[2] UNIV MASSACHUSETTS,CTR ADV MAT,DEPT PHYS,LOWELL,MA 01854

[3] INDIAN INST TECHNOL,DEPT CHEM,BOMBAY 400076,INDIA

来源：

MACROMOLECULES | 1993年 / 26卷 / 22期

关键词：

D O I：

10.1021/ma00074a017

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Changes in the FT-Raman spectrum of 1,4-bis(3-quinolyl)buta-1,3-diyne (DQ) as a function of gamma-ray dosage is used to monitor the degree of monomer to polymer conversion in a solid-state topochemical polymerization reaction. The relative intensities of the characteristic C=C peaks in the nonresonant FT-Raman spectra provide a nondestructive quantitative means to measure the conversion from monomer to polymer.

引用

页码：5954 / 5958

页数：5

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[1]

BABU KN, 1992, THESIS INDIAN I TECH

[2]

BABU KS, UNPUB

[3] AN INVESTIGATION OF THE ELECTRONIC EXCITED-STATE OF A POLYDIACETYLENE BY RESONANCE RAMAN-SPECTROSCOPY [J].