SYNTHESIS AND CHARACTERIZATION OF FLUORINATED AZO INITIATORS - APPLICATION TO ANALYSIS OF CHAIN AND REACTION IN RADICAL POLYMERIZATION OF STYRENE

被引：13

作者：

BESSIERE, JM ^{[1
]}

BOUTEVIN, B ^{[1
]}

LOUBET, O ^{[1
]}

机构：

[1] ECOLE NATL SUPER CHIM MONTPELLIER,CHIM APPL LAB,CNRS,URA 1193,8 RUE ECOLE NORMALE,F-34053 MONTPELLIER 01,FRANCE

来源：

EUROPEAN POLYMER JOURNAL | 1995年 / 31卷 / 06期

关键词：

D O I：

10.1016/0014-3057(94)00212-6

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A method for the determination of the recombination disproportionation rate during the polymerization of styrene is described. In this method an ''azo'' initiator used to prepare a perfluorinated polystyrene was first synthesized and characterized (determination of decomposition rate constant and efficiency of initiation). Then, the recombination/disproportionation rate was calculated by comparing the number-average molecular weight (DP(n)) by SEC and the fluorine content in weight of this resulting polystyrene.

引用

页码：573 / 580

页数：8

共 29 条

[1] VINYL POLYMERIZATION WITH RADIOACTIVE ALIPHATIC AZOBISNITRILE INITIATORS [J].