CATALYTIC OXIDATION-REDUCTION HYDRATION OF OLEFIN WITH MOLECULAR-OXYGEN IN THE PRESENCE OF BIS(1,3-DIKETONATO)COBALT(II) COMPLEXES

被引：86

作者：

KATO, K ^{[1
]}

YAMADA, T ^{[1
]}

TAKAI, T ^{[1
]}

INOKI, S ^{[1
]}

ISAYAMA, S ^{[1
]}

机构：

[1] MITSUI PETROCHEM IND CO LTD, BASIC RES LABS ORGAN SYNTHESIS, SODEGAURA, CHIBA 29902, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1990年 / 63卷 / 01期

关键词：

D O I：

10.1246/bcsj.63.179

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the presence of a bis(1,3-diketonato)cobalt(II) complex, various olefins are converted to the corresponding hydrated products according to the Markownikov rule on treatment with molecular oxygen in secondary alcohol (''oxidation-reduction hydration''). Removal of water formed during the hydration reaction, especially by azeotropic method, is remarkably effective to improve yields of the hydrated products based on the cobalt(II) catalyst as bis(trifluoroacetylacetonato)cobalt(II) (Co(tfa)2) or bis(2-ethoxycarbonyl-3-oxobutanalato)-cobalt(II) (Co(ecbo)2).

引用

页码：179 / 186

页数：8

共 18 条

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