RHODIUM CARBENOID MEDIATED CYCLIZATIONS .5. SYNTHESIS AND REARRANGEMENT OF CYCLIC SULFONIUM YLIDES - PREPARATION OF 6-MEMBERED AND 7-MEMBERED SULFUR HETEROCYCLES

被引：33

作者：

MOODY, CJ ^{[1
]}

TAYLOR, RJ ^{[1
]}

机构：

[1] IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM,LONDON SW7 2AY,ENGLAND

来源：

TETRAHEDRON | 1990年 / 46卷 / 18期

关键词：

D O I：

10.1016/S0040-4020(01)96017-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Treatment of diazo mercaptans with rhodium(ll) acetate gives six- and seven-membered sulphur heterocycles; diazo sulphides give cyclic sulphonium ylides, which are isolable, or rearrange, depending on the nature of the substituent on sulphur. © 1990.

引用

页码：6501 / 6524

页数：24

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