REACTIVITY OF IMINOPHOSPHORANES TOWARDS SOME SYMMETRICAL DICARBONYL DICHLORIDES - SYNTHESES AND MECHANISMS

被引：35

作者：

AUBERT, T ^{[1
]}

FARNIER, M ^{[1
]}

GUILARD, R ^{[1
]}

机构：

[1] FAC SCI GABRIEL,SYNTH & ELECTROSYNTH ORGANOMET LAB,UA 33,6 BLVD GABRIEL,F-21100 DIJON,FRANCE

来源：

TETRAHEDRON | 1991年 / 47卷 / 01期

关键词：

D O I：

10.1016/0040-4020(91)80007-O

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In situ generated iminophosphoranes 1 react with dicarbonyl dihalides 2a-b and 3a-c to give known or new nitrogen heterocycles. The proposed mechanisms involve elimination of either triphenyl-phosphine oxide or dichlorotriphenylphosphorane depending upon both the iminophosphorane and the dicarbonyl compound. © 1991.

引用

页码：53 / 60

页数：8

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