REDUCTION OF KETONES WITH POLYDIBENZO-18-CROWN-6-BOROHYDRIDE

被引：1

作者：

SARKAR, A

RAO, BR

机构：

[1] Department of Applied Chemistry, Indian School of Mines, Dhanbad

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 19期

关键词：

D O I：

10.1016/S0040-4039(00)71263-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Polydibenzo-18-crown-6-(P-DB-18-C-6), a condensation polymer of dibenzo-18-crown-6 and formaldehyde has been used as support for borohydride ions in the reduction of few cyclic and acyclic ketones. The reagent has been found to be more stereoselective than dibenzo-18-crown-6-borohydride in the reduction of cyclic ketones. 4-t-butylcyclohexanone has been converted exclusively (100%) to trans-4-t-butylcyclohexanol.

引用

页码：2157 / 2160

页数：4

共 11 条

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[2]

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[3]

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[4]

HODOSAN F, 1969, REV ROUM CHIM, V14, P121