DEMONSTRATION OF OXIDATION DYES ON HUMAN HAIR

被引：14

作者：

TANADA, N

KAGEURA, M

HARA, K

HIEDA, Y

TAKAMOTO, M

KASHIMURA, S

机构：

[1] Department of Legal Medicine, Fukuoka University School of Medicine

来源：

FORENSIC SCIENCE INTERNATIONAL | 1994年 / 64卷 / 01期

关键词：

HUMAN HAIR; OXIDATION HAIR DYE; SELECTED ION MONITORING; DIAMINES; AMINOPHENOLS;

D O I：

10.1016/0379-0738(94)90237-2

中图分类号：

DF [法律]; D9 [法律]; R [医药、卫生];

学科分类号：

0301 ; 10 ;

摘要：

This paper describes a method of selected ion monitoring (SIM) analysis which can demonstrate the staining of human hair with oxidation hair dyes. Hair samples were decomposed with NaOH-Na2S2O4 solution by heating (100-degrees-C, 30 min) in a stream of nitrogen. Basic and neutral ether extracts from the reaction mixture were trifluoroacetylated with trifluoroacetic anhydride in ethyl acetate and were then analyzed by SIM. The minimum lengths of a single hair for the detection of the 5 components of oxidation hair dyes acting as indicators were 1 mm for toluene-2,5-diamine, 2 mm for p-phenylenediamine, 20 mm for p-aminophenol, 50 mm for m-aminophenol and 100 mm for o-aminophenol. This method was applied to practical cases and the results were good.

引用

页码：1 / 8

页数：8

共 3 条

[1] FORENSIC CHEMICAL STUDY ON HUMAN-HAIR .3. IDENTIFICATION OF OXIDATIVE DYES AND PRESUMPTION OF THE BRANDS FROM REMAINING COMPONENTS ON HUMAN-HAIR [J].

FUJITA, Y ;

YAMAMOTO, N ;

NAKAYAMA, M ;

KANBARA, K ;

MITSUO, N ;

MATSUMOTO, H ;

SATOH, T .

EISEI KAGAKU-JAPANESE JOURNAL OF TOXICOLOGY AND ENVIRONMENTAL HEALTH, 1989, 35 (06) :444-453

[2]

MATSUYAMA Y, 1989, 6TH HOUK KENS KENK, P151

[3] IDENTIFICATION OF HUMAN HAIR STAINED WITH OXIDATION HAIR-DYES BY GAS CHROMATOGRAPHIC-MASS SPECTROMETRIC ANALYSIS [J].

TANADA, N ;

KAGEURA, M ;

HARA, K ;

HIEDA, Y ;

TAKAMOTO, M ;

KASHIMURA, S .

FORENSIC SCIENCE INTERNATIONAL, 1991, 52 (01) :5-11

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