THE POLANYI LECTURE - THE COLORFUL WORLD OF COMPLEX-FORMING BIMOLECULAR REACTIONS

被引：161

作者：

TROE, J

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS | 1994年 / 90卷 / 16期

关键词：

D O I：

10.1039/ft9949002303

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The author's Polanyi Lecture 1992 is summarized, discussing experimental examples of complex-forming bimolecular reactions, their identification by pressure and temperature dependence as well as isotope labelling studies, and their theoretical analysis. The still fragmentary theoretical treatment involves all ingredients of unimolecular rate theory, relying heavily on quantum-chemical characterizations of reaction pathways and of the corresponding entrance and exit transition states. The reactions are often governed by rotational as well as vibrational 'channel switching'. Ion-neutral molecule and neutral-neutral molecule reactions show analogous behaviour, although quantitative differences are observed.

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页码：2303 / 2317

页数：15

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