ACTIVATIONLESS PHOTOIONIZATION REACTIONS

被引:13
作者
BURSHTEIN, AI [1 ]
MOROZOV, VA [1 ]
机构
[1] NOVOSIBIRSK STATE UNIV,NOVOSIBIRSK 630090,USSR
关键词
D O I
10.1016/0009-2614(90)85455-L
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The notion of an activationless zone appearing due to the space dispersion of the activation energy and vibronic excitation of reaction products is introduced. The effective radius viscosity dependence of pheophytin a quenching by toluquinone is compared with the theory, taking into account a strong interaction between them deep inside the activationless zone. The electron tunnelling probability is determined by fitting to experiment. © 1990.
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页码:432 / 436
页数:5
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