CYCLOPENTADIENYL RUTHENIUM(II) AND RUTHENIUM(III) COMPLEXES WITH A CHELATING 1,2-BIS(DICYCLOHEXYLPHOSPHINO)METHANE LIGAND

被引：18

作者：

JOSLIN, FL ^{[1
]}

MAGUE, JT ^{[1
]}

ROUNDHILL, DM ^{[1
]}

机构：

[1] TULANE UNIV,DEPT CHEM,NEW ORLEANS,LA 70118

来源：

POLYHEDRON | 1991年 / 10卷 / 14期

关键词：

D O I：

10.1016/S0277-5387(00)83787-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction between eta-5-cpRuCl(PPh3)2 and 1,2-bis(dicyclohexylphosphino)methane (dcpm) gives eta-5-cpRuCl(dcpm). The complex is readily oxidized to eta-5-cpRuCl(dcpm)+. Treating eta-5-cpRuCl(dcpm) with silver triflate, followed by ammonia or carbon monoxide, gives [eta-5-cpRu(NH3)(dcpm)]CF3SO3 or [eta-5-cpRu(CO)(dcpm)]CF3SO3, respectively. Metathetical replacement of chloride with LiAlH4 gives eta-5-cpRuH(dcpm).

引用

页码：1713 / 1715

页数：3

共 8 条

[1]

DELZOTTO A, 1989, J CHEM SOC DA, P1045

[2]

DELZOTTO A, 1990, J CHEM SOC DA, P2515

[3] [BIS(DICYCLOHEXYLPHOSPHINO)ETHANE]PLATINUM(0) - REACTIONS WITH ALKYL, (TRIMETHYLSILYL)METHYL, ARYL, BENZYL, AND ALKYNYL CARBON HYDROGEN-BONDS [J].