RAMAN-SPECTRA OF ENDOHEDRAL FULLERENES - LI+AT-C60

被引：26

作者：

JOSLIN, CG

GRAY, CG

GOLDMAN, S

YANG, J

POLL, JD

机构：

[1] Guelph-Waterloo Program for Graduate Work in Physics, University of Guelph, Guelph

来源：

CHEMICAL PHYSICS LETTERS | 1993年 / 215卷 / 1-3期

关键词：

D O I：

10.1016/0009-2614(93)89278-P

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The inelastic depolarized light-scattering spectrum of the endohedral metallofullerene Li+ @ C60 is calculated for frequency shifts up to 1000 cm-1. In this species the motion of the charged inclusion within the buckyball cage generates an induced anisotropic polarizability through an interesting mechanism involving the hyperpolarizability B. The resulting Raman spectrum is quite intense. At room temperature, hot bands contribute significantly to the scattering.

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页码：144 / 150

页数：7

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