TETRATHIAFULVALENE PI-STACKS IN WATER

被引：18

作者：

BENZ, ME ^{[1
]}

TABAKOVIC, I ^{[1
]}

MILLER, LL ^{[1
]}

机构：

[1] UNIV MINNESOTA,DEPT CHEM,MINNEAPOLIS,MN 55455

来源：

CHEMISTRY OF MATERIALS | 1994年 / 6卷 / 04期

关键词：

D O I：

10.1021/cm00040a002

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Tetrathiafulvalene dicarboxylate was oxidized in water using potassium persulfate or a platinum anode to produce a stable cation radical. Vis-near-infrared spectra and ESR spectra showed that the cation radicals aggregated to form pi-dimers and, at concentrations above 2 mM, pi-stacks with an optical conduction band near 2400 nm.

引用

页码：351 / 352

页数：2

共 16 条

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