PASSIVATION AND CORROSION PHENOMENA ON LEAD-CALCIUM-TIN ALLOYS OF LEAD-ACID-BATTERY POSITIVE ELECTRODES

被引：35

作者：

MIRAGLIO, R

ALBERT, L

ELGHACHCHAM, A

STEINMETZ, J

HILGER, JP

机构：

[1] METALEUROP RECH,F-78193 TRUPPES,FRANCE

[2] UNIV NANCY 1,THERMODYNAM MET LAB,CNRS,ER 78,F-54506 VANDOEUVRE NANCY,FRANCE

[3] UNIV NANCY 1,CHIM SOLIDE MINERAL LAB,CNRS,URA 158,F-54506 VANDOEUVRE NANCY,FRANCE

来源：

JOURNAL OF POWER SOURCES | 1995年 / 53卷 / 01期

关键词：

LEAD-CALCIUM-TIN ALLOYS; LEAD ACID BATTERIES; PASSIVATION; CORROSION;

D O I：

10.1016/0378-7753(94)02153-T

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The corrosion behaviour of lead-calcium-tin alloys has been examined at two anodization potentials that correspond, respectively, to overcharge and to passivation by PbO conditions. The role of tin on the passivation phenomenon is examined in detail, while the evolution of hardening and microstructure is followed on the same samples, namely, grids (expanded and gravity cast) with different tin levels and strips, manufactured from primary or secondary lead.

引用

页码：53 / 61

页数：9

共 14 条

[1]

BAGSHAW N, 1988, POWER SOURCES 12, P113

[2]

BORCHERS H, 1979, METALL, V33, P936

[3] DISCONTINUOUS AND CONTINUOUS HARDENING PROCESSES IN CALCIUM AND CALCIUM TIN MICRO-ALLOYED LEAD - INFLUENCE OF SECONDARY-LEAD IMPURITIES [J].