GAS-PHASE REACTIONS OF THE HYDROPEROXIDE AND PEROXYFORMATE ANIONS

被引：17

作者：

BOWIE, JH ^{[1
]}

DEPUY, CH ^{[1
]}

SULLIVAN, SA ^{[1
]}

BIERBAUM, VM ^{[1
]}

机构：

[1] UNIV COLORADO,DEPT CHEM & BIOCHEM,BOULDER,CO 80309

来源：

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE | 1986年 / 64卷 / 06期

关键词：

Gases - Phase interfaces - Ions - Carbon dioxide - Chemical reactions;

D O I：

10.1139/v86-175

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The flowing afterglow technique has been used to study the reactions of H2- and HC3- in the gas phase. The hydroperoxide ion reacts slowly with CO to form HO-, and oxidizes CO2, OCS, CS2, NO, SO2, CH3NCO, and CH3NCS in fast reactions to form CO3-, CO2SP, COS2-, NO2-, SO3-, CH3NCO2-, and CH3NCOSP, respectively. Reactions of HO2- with certain amides and esters provide synthetic routes for a number of interesting peracyl anions. One of these, the peroxyformate ion, HCO3-, reacts with CO and NO in slow oxidation reactions to form the formate ion HCO2-. It also forms HCO2- upon reaction with acetone and pivalaldehyde, perhaps by Baeyer-Villiger oxidation.

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页码：1046 / 1051

页数：6

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