THE CHEMISTRY OF LAURENENE .12. THE STRUCTURE OF A MINOR PRODUCT FROM THE FORMIC-ACID INDUCED REARRANGEMENT OF LAUREN-1-ENE

被引:3
作者
HAYMAN, AR
PERRY, NB
WEAVERS, RT
机构
[1] UNIV OTAGO,DEPT CHEM,POB 56,DUNEDIN,NEW ZEALAND
[2] UNIV CANTERBURY,DEPT CHEM,CHRISTCHURCH 1,NEW ZEALAND
[3] UNIV EDINBURGH,DEPT CHEM,EDINBURGH EH9 3JJ,MIDLOTHIAN,SCOTLAND
关键词
D O I
10.1071/CH9901061
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Rearrangement of lauren-l-ene (1) with formic acid gives a trisubstituted alkene (4) in addition to the previously characterized tetrasubstituted alkene (3). The structure was determined by n.m.r. studies on (4) and the derived diol (5). Alkene (4) contains a new tetracyclic carbon skeleton which comprises one six-membered ring and three five-membered rings. © 1990 ASEG.
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页码:1061 / 1069
页数:9
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