ON THE REGIOSELECTIVITY OF COUPLING OF SUBSTITUTED ALLYL RADICALS - STERIC VERSUS FMO CONTROL

被引：15

作者：

PASTO, DJ

LHERMINE, G

机构：

[1] Department of Chemistry, Biochemistry University of Notre Dame, Notre Dame

来源：

TETRAHEDRON | 1993年 / 49卷 / 16期

关键词：

ALLYL; RADICALS; SULFENATES; COUPLING; REGIOSELECTIVITY; STERIC CONTROL; FMO CONTROL;

D O I：

10.1016/S0040-4020(01)90155-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The photo-induced decomposition of substituted-homoallylic 4-nitrobenzenesulfenates produces substituted allyl radicals which undergo dimerization and coupling with the 4-nitrobenzenethiyl radical. The regioselectivity of the dimerization of the allyl radicals is controlled by both steric and FMO properties depending on the nature of the substituent.

引用

页码：3259 / 3272

页数：14

共 11 条

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