REGIOSELECTIVE ZIRCONIUM-MEDIATED CROSS-COUPLING OF N-METHYL-N-PROPARGYL ANILINE AND ALKENES

被引：11

作者：

BARLUENGA, J

SANZ, R

FANANAS, FJ

机构：

[1] Instituto Universitario de Química Organometálica Enrique Moles, Universidad de Oviedo, 33071-Oviedo

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1995年 / 50卷 / 03期

关键词：

REGIOSELECTIVE CROSS COUPLING; PROPARGYLAMINE-ZIRCONOCENE COMPLEX; ZIRCONACYCLOPENTENE;

D O I：

10.1515/znb-1995-0302

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

N-(2-bromoallyl)-N-methylaniline 1 is easily converted into the propargylamine-zirconocene complex 3 via loss of methane from 2-[zirconocene(methyl)]allyl amine 2. Regioselective insertion reactions with alkenes and benzophenone afford, after iodinolysis, products 4-10.

引用

页码：312 / 314

页数：3

共 17 条

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