ACYLATION OF ACTIVATED AROMATIC SUBSTRATES UNDER MILD CONDITIONS WITH (RCO)(2)O/ME(2)S/BF3

被引：29

作者：

KISELYOV, AS ^{[1
]}

HARVEY, RG ^{[1
]}

机构：

[1] UNIV CHICAGO,BEN MAY INST,CHICAGO,IL 60637

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 23期

关键词：

D O I：

10.1016/0040-4039(95)00699-D

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient procedure for acylation and perfluoroacylation of activated aromatic substrates under mild conditions using the system (RCO)(2)O/Me(2)S/BF3 in CH2Cl2 is described. It is believed that dimethylacylsulfonium salts, RCOSMe(2)+ RCO(2)BF(3)-, are the active acylating agents.

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页码：4005 / 4008

页数：4

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