COPPER-COMPLEXES OF 1,1-DI(2-PYRIDYL)ETHYL METHYL-ETHER - X-RAY CRYSTAL-STRUCTURES AND REACTIONS WITH DIOXYGEN

被引：24

作者：

BHADURI, S ^{[1
]}

SAPRE, NY ^{[1
]}

JONES, PG ^{[1
]}

机构：

[1] TECH UNIV BRAUNSCHWEIG,INST ANORGAN & ANALYT CHEM,W-3300 BRAUNSCHWEIG,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1991年 / 10期

关键词：

D O I：

10.1039/dt9910002539

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The mixed-valence complexes [Cu(II)L3(1)][Cu2lI4] (L1 = di-2-pyridyl ketone), [Cu(II)(HL2)2][Cu2lI4] [HL2 = 1,1-di(2-pyridyl)ethanol] and [Cu(II)L2(3)][Cu2lI4] [L3 = 1,1-di(2-pyridyl)ethyl methyl ether] have been isolated from the reactions of CuI with the respective ligands. On interactions with dioxygen the last two complexes are oxidised to [Cu(II)2L(2)2I2] and [Cu(II)2L2(3)(OH)2][Cu(I)I3] respectively. The X-ray crystal structures of [Cu(II)L2(3)][Cu(I)2I4] and [Cu(II)2L2(3)(OH)2][Cu(I)I3] are reported.

引用

页码：2539 / 2543

页数：5

共 14 条

[1] COPPER-COMPLEXES OF 1,1-DI-2-PYRIDYLETHANOL - X-RAY STRUCTURES AND REACTION WITH OXYGEN [J].

BASU, A ;

BHADURI, S ;

SAPRE, NY ;

JONES, PG .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (22) :1724-1725

[2] MOLECULES WITH AN M4X4 CORE .4. CRYSTALLOGRAPHIC DETECTION OF A STEP CONFIGURATION FOR CU4I4 CORE IN TETRAMERIC TRIPHENYLPHOSPHINECOPPER(I) IODIDE, [PPH3CUI]4 [J].

CHURCHILL, MR ;

DEBOER, BG ;

DONOVAN, DJ .

INORGANIC CHEMISTRY, 1975, 14 (03) :617-623

[3] REACTIVITY OF THE LACCASE TRINUCLEAR COPPER ACTIVE-SITE WITH DIOXYGEN - AN X-RAY ABSORPTION-EDGE STUDY [J].

COLE, JL ;

TAN, GO ;

YANG, EK ;

HODGSON, KO ;

SOLOMON, EI .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (06) :2243-2249

[4]

COLE JL, 1990, J AM CHEM SOC, P112

[5] SYNTHESIS AND STRUCTURAL INVESTIGATION OF IODOCUPRATES(1) .7. (CU36I56)20- - A NOVEL POLYANION IN THE COMPOUND (PYH)2(CU3I5) [J].

HARTL, H ;

FUCHS, J .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1986, 25 (06) :569-570

[6] PREPARATION AND CHARACTERIZATION OF TETRAPHENYLPHOSPHONIUM AND TETRAPHENYLARSONIUM HALOGENOARGENTATES(I), INCLUDING A NEW IODOARGENTATE(I) CLUSTER, [AG4I8]4-, CONTAINING 3-CO-ORDINATED AND 4-CO-ORDINATED SILVER(I) [J].

HELGESSON, G ;

JAGNER, S .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (08) :2413-2420

[7] SYNTHESES AND STRUCTURE ANALYSES OF IODOCUPRATES(I) .11. CRYSTAL-STRUCTURE OF TL4CU2I6 [J].

HOYER, M ;

HARTL, H .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1990, 587 (08) :23-28

[8] COPPER(I) DIOXYGEN REACTIVITY .2. REACTION OF A 3-COORDINATE COPPER(I) COMPLEX WITH O-2, WITH EVIDENCE FOR A BINUCLEAR OXO COPPER(II) SPECIES - STRUCTURAL CHARACTERIZATION OF A PARALLEL-PLANAR DIHYDROXO-BRIDGED DIMER [J].

KARLIN, KD ;

GULTNEH, Y ;

HAYES, JC ;

ZUBIETA, J .

INORGANIC CHEMISTRY, 1984, 23 (05) :519-521

[9]

KARLIN KD, 1990, INORG CHEM, V29, P2551

[10] CHEMISTRY OF HETEROCYCLIC-COMPOUNDS .117. X-RAY SINGLE-CRYSTAL STRUCTURE DETERMINATION OF COPPER(II), COBALT(II), AND NICKEL(II) COMPLEXES OF 2,2-BIS(2-PYRIDYL)-1,3-DIOXOLANE AND 2,2-BIS(6-METHYL-2-PYRIDYL)-1,3-DIOXOLANE [J].

NEWKOME, GR ;

TAYLOR, HCR ;

FRONCZEK, FR ;

GUPTA, VK .

INORGANIC CHEMISTRY, 1986, 25 (08) :1149-1154

← 1 2 →