PROOF OF A RADICAL TRANSANNULAR HYDROGEN MIGRATION IN THE LONGIFOLENE SERIES

被引：13

作者：

BOIVIN, J ^{[1
]}

DASILVA, E ^{[1
]}

OURISSON, G ^{[1
]}

ZARD, SZ ^{[1
]}

机构：

[1] CNRS,INST CHIM SUBST NAT,F-91198 GIF SUR YVETTE,FRANCE

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 17期

关键词：

D O I：

10.1016/S0040-4039(00)97400-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Radical decarboxylation of isolongifolic acid 3a affords in good yield the thio-ether 4 through a reaction involving a clean 1,5-transannular hydrogen shift. The thio-ether 4 was further converted in almost quantitative yield into the olefin 7 through sequential oxidation-elimination. © 1990.

引用

页码：2501 / 2504

页数：4

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