HOMOCHIRAL 1-METHOXY-3-SULFINYL-1,3-BUTADIENES DERIVED FROM 10-MERCAPTOISOBORNEOL

被引：38

作者：

AVERSA, MC ^{[1
]}

BONACCORSI, P ^{[1
]}

GIANNETTO, P ^{[1
]}

JAFARI, SMA ^{[1
]}

JONES, DN ^{[1
]}

机构：

[1] UNIV SHEFFIELD,DEPT CHEM,SHEFFIELD S3 7HF,S YORKSHIRE,ENGLAND

来源：

TETRAHEDRON-ASYMMETRY | 1992年 / 3卷 / 06期

关键词：

D O I：

10.1016/S0957-4166(00)80505-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Simple syntheses of homochiral (Z)- and (E)-1-methoxy-3-alkylsulfinyl-1,3-butadienes were provided by the cycloaddition of (IS)-d-isobornyl-10-sulfenic acid to (Z)- and (E)-1-methoxybut-1-en-3-yne. Asymmetric induction pertained for such cycloadditions, which also provided homochiral dienes from 1-ethynylcyclohex-1-ene.

引用

页码：701 / 704

页数：4

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