RATE OF ADSORPTION TO AND DESORPTION FROM A LANGMUIR SURFACE - THE CASE OF ZERO ACTIVATION BARRIER TO ADSORPTION WITHOUT DISSOCIATION

被引：6

作者：

BOUDART, M

LOFFLER, DG

机构：

[1] Department of Chemical Engineering, Stanford University, Stanford, 94305, California

来源：

CATALYSIS LETTERS | 1990年 / 6卷 / 3-6期

关键词：

Desorption from a Langmuir surface; pre-exponential factor for desorption rate constant;

D O I：

10.1007/BF00763997

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Many rate constants of elementary steps on single crystals have been measured. Their pre-exponential factors can now be compared to those calculated by transition state theory. Such a calculation is presented in this Letter with due attention to microscopic reversibility, standard states, and configurational entropy. © 1990 J.C. Baltzer A.G. Scientific Publishing Company.

引用

页码：317 / 320

页数：4

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[3]

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[5]

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[6]

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PAVLICEK, J ;

KNOR, Z .

CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 1988, 30 (04) :501-517

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