OXYGENATION OF SILYL ENOL ETHERS AND SILYL KETENE ACETALS WITH MOLECULAR-OXYGEN AND ALDEHYDE CATALYZED BY NICKEL(II) COMPLEX - A CONVENIENT METHOD FOR THE PREPARATION OF ALPHA-HYDROXY CARBONYL-COMPOUNDS

被引：45

作者：

TAKAI, T

YAMADA, T

RHODE, O

MUKAIYAMA, T

机构：

来源：

CHEMISTRY LETTERS | 1991年 / 02期

关键词：

D O I：

10.1246/cl.1991.281

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the presence of a catalytic amount of nickel(II) complex, silyl enol ethers and silyl ketene acetals are smoothly oxygenated by the combined use of molecular oxygen and aldehyde to afford alpha-siloxy carbonyl compounds via possible intermediates, siloxy expoxides. And on treatment of the alpha-siloxy carbonyl compounds with potassium fluoride alpha-hydroxy carbonly compounds are obtained in good to high yields.

引用

页码：281 / 284

页数：4

共 16 条

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