2-BENZOTHIAZOLYLCHLOROMETHYLLITHIUM - SYNTHESIS OF OXIRANES

被引：22

作者：

FLORIO, S ^{[1
]}

TROISI, L ^{[1
]}

机构：

[1] UNIV LECCE,DIPARTIMENTO BIOL,I-73100 LECCE,ITALY

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 51期

关键词：

D O I：

10.1016/S0040-4039(00)74787-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Deprotonation of 2-chloromethylbenzothiazole 1 with lithium diisopropylamide (LDA) in tetrahydrofuran (THF) at -78-degrees-C gives a red solution of 2-benzothiazolylchloromethyllithium 2, which couples with carbonyl compounds furnishing oxiranes 3.

引用

页码：7953 / 7956

页数：4

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