HIGH-RESOLUTION INFRARED-SPECTRA OF OZONE IN THE 2300-2600 CM(-1) REGION

被引：31

作者：

BARBE, A ^{[1
]}

SULAKSHINA, O ^{[1
]}

PLATEAUX, JJ ^{[1
]}

HAMDOUNI, A ^{[1
]}

BOUAZZA, S ^{[1
]}

机构：

[1] TOMSK ATMOSPHER OPT INST,THEORET SPECT LAB,TOMSK,RUSSIA

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 1995年 / 170卷 / 01期

关键词：

D O I：

10.1006/jmsp.1995.1068

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The spectra of ozone in the region 2300-2600 cm(-1) have been recorded with the high-resolution Fourier transform spectrometer of Reims. A White-type cell with a length of 36 m and pressure of 50 Torr of ozone has been used. This region corresponds mainly to the weak bands nu(1) + 2 nu(2) and 2 nu(2) + nu(3), which were previously analyzed with a much lower amount of ozone. Now high values of J and K-a have been observed up to 55 and 11, respectively. The final fit on the 615 energy levels is very satisfactory, 0.39 X 10(-3) cm-l, equal to experimental accuracy. Good agreement is also obtained for line intensities. Furthermore, the two difference bands 3 nu(3) - nu(2) and nu(1) + 2 nu(3) - nu(2) have been observed for the first time and their transition moments are given. (C) 1995 Academic Press, Inc.

引用

页码：244 / 250

页数：7

共 9 条

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