CONFORMATIONAL EFFECTS IN ELEMENTARY STEPS IN CATALYTIC REACTIONS - OXIDATIVE ADDITION OF 3-BROMOPROP-1-ENE TO A PALLADIUM(II) METALLACYCLIC COMPLEX

被引：74

作者：

CATELLANI, M ^{[1
]}

MANN, BE ^{[1
]}

机构：

[1] UNIV SHEFFIELD,DEPT CHEM,SHEFFIELD S3 7HF,S YORKSHIRE,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 390卷 / 02期

关键词：

D O I：

10.1016/0022-328X(90)85036-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The solution structure of an η1-allylpalladium(IV) complex formed by oxidative addition of bromopropene to a palladium(II) metallacyclic species has been determined by 1H NMR spectroscopy. A cis attack from the less-hindered side is implied. © 1990.

引用

页码：251 / 255

页数：5

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