EPOXY-RESINS BASED ON AROMATIC GLYCIDYLAMINES .3. KINETICS OF INTRAMOLECULAR CYCLIZATION OF N,N-BIS(2-HYDROXY-3-CHLOROPROPYL)ANILINE

被引：6

作者：

PODZIMEK, S ^{[1
]}

DOBAS, I ^{[1
]}

SVESTKA, S ^{[1
]}

EICHLER, J ^{[1
]}

KUBIN, M ^{[1
]}

机构：

[1] CZECHOSLOVAK ACAD SCI, INST MACROMOLEC CHEM, CS-16206 PRAGUE 6, CZECHOSLOVAKIA

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 1991年 / 42卷 / 03期

关键词：

D O I：

10.1002/app.1991.070420322

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The course of intramolecular cyclization of N,N-bis(2-hydroxy-3-chloropropyl) aniline (DCHA) was followed by HPLC. The rate constants (at 70, 85, 100, and 115-degrees-C) and the Arrhenius parameters for individual reaction steps were determined. The resulting product was isolated by semipreparative HPLC and its structure was confirmed by NMR spectroscopy. Attention was also paid to the different reactivity of DCHA diastereoisomers.

引用

页码：791 / 794

页数：4

共 4 条

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[3]

PODZIMEK S, IN PRESS J APPL PO 1

[4]

PODZIMEK S, IN PRESS J APPL PO 2

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