IMPROVED ENANTIOSELECTIVITY IN ASYMMETRIC DIHYDROXYLATIONS OF TERMINAL OLEFINS USING PYRIMIDINE LIGANDS

被引：235

作者：

CRISPINO, GA ^{[1
]}

JEONG, KS ^{[1
]}

KOLB, HC ^{[1
]}

WANG, ZM ^{[1
]}

XU, DQ ^{[1
]}

SHARPLESS, KB ^{[1
]}

机构：

[1] Scripps Res Inst, DEPT CHEM, 10666 N TORREY PINES RD, LA JOLLA, CA 92037 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1993年 / 58卷 / 15期

关键词：

D O I：

10.1021/jo00067a002

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Bis-cinchona alkaloid substituted pyrimidine ligands were found to give improved enantioselectivity in the osmium-catalyzed asymmetric dihydroxylation (AD) of monosubstituted terminal olefins.

引用

页码：3785 / 3786

页数：2

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[5] THE OSMIUM-CATALYZED ASYMMETRIC DIHYDROXYLATION - A NEW LIGAND CLASS AND A PROCESS IMPROVEMENT
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[6] SHARPLESS KB, UNPUB

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