HIGH-PRESSURE FOURIER-TRANSFORM INFRARED-SPECTROSCOPY STUDY OF THE DIELS-ALDER REACTION OF ISOPRENE AND MALEIC-ANHYDRIDE IN SUPERCRITICAL CARBON-DIOXIDE

被引：34

作者：

IKUSHIMA, Y ^{[1
]}

SAITO, N ^{[1
]}

ARAI, M ^{[1
]}

机构：

[1] TOHOKU UNIV, CHEM RES INST NON AQUEOUS SOLUT, AOBA KU, SENDAI, MIYAGI 980, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1991年 / 64卷 / 01期

关键词：

D O I：

10.1246/bcsj.64.282

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A high-pressure FTIR spectroscopy was used to make an in situ study on the Diels-Alder reaction of isoprene and maleic anhydride catalyzed with aluminum chloride in supercritical carbon dioxide at 306 K and 7.45 and 7.85 MPa, suggesting a two-step mechanism and showing a pressure effect.

引用

页码：282 / 284

页数：3

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