EPR-SPECTRUM OF AGPF3

被引：3

作者：

HISTED, M

HOWARD, JA

JONES, R

TOMIETTO, M

JOLY, HA

机构：

[1] NATL RES COUNCIL CANADA,STEACIE INST MOLEC SCI,OTTAWA K1A 0R9,ONTARIO,CANADA

[2] LAURENTIAN UNIV,DEPT CHEM,SUDBURY P3E 2C6,ONTARIO,CANADA

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1992年 / 96卷 / 03期

关键词：

D O I：

10.1021/j100182a023

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The mononuclear monoligand silver(0) complex AgPF3 has been prepared by reaction of Ag-107 atoms with PF3 at 77 K in an adamantane matrix on a rotating cryostat. This species has the magnetic parameters a107(1) = 1685 +/- 0.3 MHz, a31(1) = 311 +/- 0.1 MHz, a19(3) = 37.3 +/- 0.1 MHz, and g = 2.0020 +/- 0.0001. It is a Ag-centered radical with a 2A1 ground state in the point group C30 formed by interaction of PF3 with Ag rather than a phosphorus-centered radical formed by addition of Ag to PF3.

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页码：1144 / 1146

页数：3

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