(1,4,7-TRIS(4-TERT-BUTYL-2-MERCAPTOBENZYL)-1,4,7-TRIAZACYCLONONANE)IRON(III) - A MODEL FOR THE IRON SULFUR CENTER IN NITRILE HYDRATASE FROM BREVIBACTERIUM, SP

被引：71

作者：

BEISSEL, T

BURGER, KS

VOIGT, G

WIEGHARDT, K

BUTZLAFF, C

TRAUTWEIN, AX

机构：

[1] RUHR UNIV BOCHUM,LEHRSTUHL ANORGAN CHEM 1,W-4630 BOCHUM,GERMANY

[2] MED UNIV LUBECK,INST PHYS,W-2400 LUBECK,GERMANY

来源：

INORGANIC CHEMISTRY | 1993年 / 32卷 / 02期

关键词：

D O I：

10.1021/ic00054a002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Stable six-coordinate iron(III) complexes of the pendant arm macrocycles 1,4,7-tris(4-tert-butyl-2-mercaptobenzyl)-1,4,7-triazacyclononane and 1,4,7-tris(mercaptopropyl)-1,4,7-triazacyclononane each of which provide a fac-N3S3 donor set have been synthesized and characterized by UV-vis and ESR spectroscopy. These complexes serve as a structural model for the bacterial enzyme nitrile hydratase from Brevibacterium, sp.

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页码：124 / 126

页数：3

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