RESOLUTION OF ENANTIOMERS OF CIS-FUSED AND TRANS-FUSED C-60-ENONE [2+2] PHOTOADDUCTS

被引：58

作者：

WILSON, SR ^{[1
]}

WU, YH ^{[1
]}

KAPRINIDIS, NA ^{[1
]}

SCHUSTER, DI ^{[1
]}

WELCH, CJ ^{[1
]}

机构：

[1] REGIS CHEM CO,MORTON GROVE,IL 60053

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1993年 / 58卷 / 24期

关键词：

D O I：

10.1021/jo00076a007

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Enantiomers of the mixture of cis and trans photocycloadducts of C60 and 3-methylcyclohexenone were separated by HPLC on the chiral stationary phase (S,S)-Whelk-O; chiroptical properties indicate that the fullerene moiety in the strained trans cycloadducts has a skewed pi-system with local C2 symmetry.

引用

页码：6548 / 6549

页数：2

共 26 条

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