THE FIRST EXAMPLE OF MULTIPLE OXIDATION REACTIONS OF ETA(6)-ALKYLATED ANILINE-ETA(5)-CYCLOPENTADIENYLIRON COMPLEXES

被引：6

作者：

ABDELAZIZ, AS

EPP, KM

机构：

[1] Department of Chemistry, University of Winnipeg, Winnipeg

来源：

POLYHEDRON | 1995年 / 14卷 / 07期

关键词：

D O I：

10.1016/0277-5387(94)00496-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A unique synthetic route to cyclopentadienyliron complexes of functionalized nitrobenzene has been developed via the successive oxidation of the amine and the alkyl groups of their corresponding aniline complexes. Nucleophilic aromatic substitution reactions of the nitroarene complexes with a number of nucleophiles gave rise to monoiron and diiron complexes with various alkyl and keto substituents.

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页码：957 / 960

页数：4

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