USE OF MICRO-RAMAN SPECTROSCOPY FOR THE QUANTITATIVE-DETERMINATION OF POLYETHYLENE DENSITY USING PARTIAL LEAST-SQUARES CALIBRATION

被引:48
作者
WILLIAMS, KPJ [1 ]
EVERALL, NJ [1 ]
机构
[1] ICI PLC,WILTON RES CTR,MIDDLESBROUGH TS90 8JE,CLEVELAND,ENGLAND
关键词
D O I
10.1002/jrs.1250260606
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
A series of polyethylene samples were analysed using a micro Raman system. The data were analysed using a commercial partial least-squares package and correlated with the polymer density, A correlation coefficient of up to 0.98 was obtained, depending on the spectral region used, A standard error of prediction of 2.15 kg m(-3) was obtained and the densities of 'blind' samples were predicted with good accuracy.
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页码:427 / 433
页数:7
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