THE CLUSTER ANION [RU6H(CO)15S3]- - A PLANAR HEXANUCLEAR METAL FRAMEWORK WITH ALMOST PERFECT C3V SYMMETRY

被引：21

作者：

BODENSIECK, U ^{[1
]}

STOECKLIEVANS, H ^{[1
]}

SUSSFINK, G ^{[1
]}

机构：

[1] UNIV NEUCHATEL,INST CHIM,CH-2000 NEUCHATEL,SWITZERLAND

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 09期

关键词：

D O I：

10.1002/anie.199111261

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A mu-3-hydrido- and three mu-3-sulfido ligands cap the hexanuclear metal array of the cluster anion 1 "below" and "above" the Ru6-triangular surface. This highly symmetric, aesthetically stimulating complex 1 is formed upon reaction of [Ru3(CO)12] and tetramethylthiourea under pressure and can be precipitated as the tetramethylformamidinium salt from dichloromethane. [GRAPHICS]

引用

页码：1126 / 1127

页数：2

共 9 条

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