SIMPLE PROCEDURE FOR REDUCTIVE COUPLING OF STEROIDS WITH A CROSS CONJUGATED DIENONE SYSTEM

被引：15

作者：

SCHMIDT, A ^{[1
]}

BECKERT, R ^{[1
]}

WEISS, D ^{[1
]}

机构：

[1] UNIV JENA,DEPT ORGAN CHEM,HUMBOLDTSTR 10,O-6900 JENA,GERMANY

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 30期

关键词：

D O I：

10.1016/S0040-4039(00)74243-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A simple procedure was found to dimerize cross conjugated dienones to the corresponding olefins. In contrast to the McMurry reaction this variant works without titanium halides. Bis-steroids which may be of pharmacological importance are prepared in high yields.

引用

页码：4299 / 4300

页数：2