PRESSURE VOLUME BEHAVIOR OF 2 CAPILLARY LIQUIDS

被引：4

作者：

MACHIN, WD

STUCKLESS, JT

机构：

[1] Memorial Univ of Newfoundland, Dep, of Chemistry, St. John's, Newfoundl,, Can, Memorial Univ of Newfoundland, Dep of Chemistry, St. John's, Newfoundl, Can

来源：

JOURNAL OF COLLOID AND INTERFACE SCIENCE | 1985年 / 108卷 / 01期

关键词：

EQUATIONS OF STATE - LIQUIDS - Physical Chemistry - SILICA GEL;

D O I：

10.1016/0021-9797(85)90234-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Adsorption isotherms for trichlorofluoromethane and carbon tetrachloride on a commercial silica gel are reported. All isotherms are type I and exhibit hysteresis. At relative pressures greater than the lower closure point of the hysteresis loop the adsorbates can be regarded as capillary liquids at negative pressure. The molar volumes of the capillary liquids are greater than those of the corresponding bulk liquids, and the dependence of molar volume on pressure is well represented by an equation of state proposed by R. J. Speedy (J. Phys. Chem. 80, 982, 1982). The compressibilities of the capillary liquids are greater than those of the corresponding bulk liquids.

引用

页码：46 / 49

页数：4

共 10 条

[1] SCANNING STUDIES ON CAPILLARY CONDENSATION AND EVAPORATION OF NITROGEN .2. ANALYSIS OF ASCENDING AND DESCENDING SCANNING CURVES WITHIN B-TYPE HYSTERESIS LOOPS [J].

BROEKHOFF, JCP ;

VANBEEK, WP .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1979, 75 :42-&

[2] LOWER CLOSURE POINT IN ADSORPTION HYSTERESIS OF CAPILLARY CONDENSATION TYPE [J].

BURGESS, CGV ;

EVERETT, DH .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1970, 33 (04) :611-&

[3] LOW-PRESSURE STUDIES OF ISOTHERMAL COMPRESSIBILITIES AND SPECIFIC VOLUMES OF ORGANIC LIQUIDS [J].

BURKAT, RK ;

RICHARD, AJ .

JOURNAL OF CHEMICAL THERMODYNAMICS, 1975, 7 (03) :271-277

[4]

Gregg S. J., 1982, ADSORPTION SURFACE A, P154

[5] COMMENTS ON LIMITS OF APPLICABILITY OF MECHANISM OF CAPILLARY CONDENSATION [J].

KADLEC, O ;

DUBININ, MM .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1969, 31 (04) :479-&

[6] DENSITIES OF LIQUID CH4-AXA (X=BR,I) AND CH4-(A+B+C+D)FACIBRCID HALOMETHANES [J].

KUDCHADKER, AP ;

KUDCHADKER, SA ;

PATNAIK, PR ;

MISHRA, PP .

JOURNAL OF PHYSICAL AND CHEMICAL REFERENCE DATA, 1978, 7 (02) :425-439

[7] CAPILLARY-CONDENSED WATER IN SILICA-GEL [J].

MACHIN, WD ;

STUCKLESS, JT .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1985, 81 :597-600

[8]

MCGOWAN JC, CRC HDB CHEM PHYSICS, pF16

[9] REPORTING PHYSISORPTION DATA FOR GAS SOLID SYSTEMS - WITH SPECIAL REFERENCE TO THE DETERMINATION OF SURFACE-AREA AND POROSITY [J].

SING, KSW .

PURE AND APPLIED CHEMISTRY, 1982, 54 (11) :2201-2218

[10] STABILITY-LIMIT CONJECTURE - AN INTERPRETATION OF THE PROPERTIES OF WATER [J].

SPEEDY, RJ .

JOURNAL OF PHYSICAL CHEMISTRY, 1982, 86 (06) :982-991

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