HYDROTHERMAL SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF (VO)(2)(PO4)(2)H2PO4-CENTER-DOT-N2C2H10, A NEW 3-DIMENSIONAL, ORGANICALLY TEMPLATED MIXED-VALENCE VANADIUM PHOSPHATE RELATED TO THE 2VOSO(4)CENTER-DOT-H2SO4 STRUCTURE

被引：35

作者：

HARRISON, WTA ^{[1
]}

HSU, K ^{[1
]}

JACOBSON, AJ ^{[1
]}

机构：

[1] UNIV HOUSTON,DEPT CHEM,HOUSTON,TX 77204

来源：

CHEMISTRY OF MATERIALS | 1995年 / 7卷 / 11期

关键词：

D O I：

10.1021/cm00059a005

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The hydrothermal synthesis and structural characterization of (VO)(2)(PO4)(2)H2PO4 . N2C2H10, which is built up from (VO6)-O-IV, (VO6)-O-V, PO4, and H2PO4 polyhedra, connected via V-O-P bonds, are described. The doubly protonated ethylenediamine dication provides charge compensation. The relationship between this phase and the 2VOSO(4) . H2SO4 structure type is discussed.

引用

页码：2004 / &

共 16 条

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