CORALLOIDOLIDE-F, THE 1ST EXAMPLE OF A 2,6-CYCLIZED CEMBRANOLIDE - ISOLATION FROM THE MEDITERRANEAN ALCYONACEAN CORAL ALCYONIUM-CORALLOIDES

被引：11

作者：

DAMBROSIO, M ^{[1
]}

GUERRIERO, A ^{[1
]}

PIETRA, F ^{[1
]}

机构：

[1] UNIV TRENT,IST CHIM,I-38050 TRENT,ITALY

来源：

HELVETICA CHIMICA ACTA | 1990年 / 73卷 / 04期

关键词：

D O I：

10.1002/hlca.19900730406

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Mediterranean alcyonacean Alcyonium ( = Parerythropodium) coralloides (Pallas, 1766) is shown here to contain coralloidolide F ( = (+)‐(3a‐R*, 7R*, 8R*, 9R*, 12R*, 12aS*)‐8,9‐epoxy‐1,3a,6,7,8,9,10,11,12,12a‐decahydro‐3a‐hydroxy‐12‐isopropenyl‐2,5‐dimethyl‐1‐oxocyclopfintacycloundecene‐9,7‐carbolactone; (+)‐2), the first example of a 2,6‐cyclized cembranolide. Structural assignments are mainly based on ID and 2D NMR and MS data. Copyright © 1990 Verlag GmbH & Co. KGaA, Weinheim

引用

页码：804 / 807

页数：4

共 12 条

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