IMMOBILIZATION OF HRH(CO)(P(META-C6H4SO3NA)3)3 ON AN ANION-EXCHANGE RESIN FOR THE HYDROFORMYLATION OF HIGHER OLEFINS

被引：18

作者：

TOTH, I ^{[1
]}

HANSON, BE ^{[1
]}

GUO, I ^{[1
]}

DAVIS, ME ^{[1
]}

机构：

[1] VIRGINIA POLYTECH INST & STATE UNIV,DEPT CHEM ENGN,BLACKSBURG,VA 24061

来源：

CATALYSIS LETTERS | 1991年 / 8卷 / 2-4期

关键词：

WATER SOLUBLE RHODIUM COMPLEX; ANION EXCHANGE RESIN CATALYST SUPPORT; IMMOBILIZATION OF RHODIUM COMPLEX;

D O I：

10.1007/BF00764118

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The anion exchange resin Amberlyst, A-26, forms an efficient matrix for the immobilization of the water soluble complex, HRh(CO)(m-C6H4SO3Na)3)3. Catalysis proceeds in anhydrous alcohol solvents which allows the conversion of water insoluble olefins to aldehydes. Activities and selectivities are similar to both supported aqueous phase catalysts and to the neutral complex, HRh(CO)(PPh3)3 in non-aqueous solvents. The catalyst preparation minimizes the quantity of water in the supported catalyst; the lack of water is thought to be responsible for an increase in catalyst stability toward oxidation.

引用

页码：209 / 214

页数：6

共 21 条

[1] SUPPORTED AQUEOUS-PHASE CATALYSTS [J].

ARHANCET, JP ;

DAVIS, ME ;

MEROLA, JS ;

HANSON, BE .

JOURNAL OF CATALYSIS, 1990, 121 (02) :327-339

[2] HYDROFORMYLATION BY SUPPORTED AQUEOUS-PHASE CATALYSIS - A NEW CLASS OF HETEROGENEOUS CATALYSTS [J].

ARHANCET, JP ;

DAVIS, ME ;

MEROLA, JS ;

HANSON, BE .

NATURE, 1989, 339 (6224) :454-455

[3]

ARHANCET JP, IN PRESS J CATAL

[4]

ARHANCET JP, 1982, Patent No. 4347003

[5]

BOROWSKI AF, 1978, NOUV J CHIM, V2, P137

[6] HYDROFORMYLATION OF OLEFINS WITH THE WATER-SOLUBLE HRH(CO)[P(M-C6H4SO3NA)3]3 IN SUPPORTED AQUEOUS-PHASE - IS IT REALLY AQUEOUS [J].

HORVATH, IT .

CATALYSIS LETTERS, 1990, 6 (01) :43-48

[7] RHODIUM(I) AND RUTHENIUM(II) COMPLEXES OF SULFONATED TRIPHENYLPHOSPHINE IMMOBILIZED ON ION-EXCHANGE MATERIALS [J].

JOO, F ;

BECK, MT .

JOURNAL OF MOLECULAR CATALYSIS, 1984, 24 (02) :135-145

[8]

KIM L, 1979, Patent No. 4179403

[9]

KIM L, 1982, Patent No. 4317936

[10]

KIM L, 1979, Patent No. 4179402

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