CORYMBOTINS A-I - HIGHLY OXIDIZED KOLOVANE DERIVATIVES FROM CASEARIA-CORYMBOSA

被引:35
作者
CHEN, TB [1 ]
WIEMER, DF [1 ]
机构
[1] UNIV IOWA,DEPT CHEM,IOWA CITY,IA 52242
来源
JOURNAL OF NATURAL PRODUCTS | 1991年 / 54卷 / 06期
关键词
D O I
10.1021/np50078a019
中图分类号
Q94 [植物学];
学科分类号
071001 ;
摘要
A family of kolovane and norkolovane diterpenoids 6-14 has been isolated from leaves of the tropical tree Casearia corymbosa. These structures have been assigned based on data provided by various spectroscopic techniques, including a variety of 2D nmr experiments. Each of these nine compounds contains an unusual, highly oxidized C ring that may be viewed as a protected dialdehyde; the norkolovanes contain an additional aldehyde group as well.
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页码:1612 / 1618
页数:7
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